Department of Chemistry
Oregon State University



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The 2008 CH 121 final exam cover sheet is identical to the 2007 final exam cover sheet. Our CH 121 final exam is scheduled for 7:30am on Tuesday, December 9, 2008. The exam period is from 7:30-9:20am (Good Morning!). The exam is approximately 40 questions. About 1/3 of the questions cover the Exam 1 objectives (read as: similar to Exam 1 questions). About 1/3 of the questions cover the Exam 2 objectives (read as: similar to Exam 2 questions). About 1/3 of the questions cover the Quantum objectives (our material from Chapter 7 and part of Chapter 8). Students have found it valuable to print out and retake Exam 1 from October and Exam 2 from November.  These and the keys are still available from the Exams Information link (http://www.chem.orst.edu/courses/ch121-3/ch121/ch121examinformation/ch121exam.htm). Check your solutions and brush up on these concepts. To study for the last third of the exam, practice past final exams (http://www.chem.orst.edu/courses/ch121-3/ch121/ch121examinformation/ch121exam.htm), complete OWLs, complete Worksheets, and discuss concepts.

Many students significantly increase their course standing with a tremendous final exam score. The exam policy is:

If you write a higher percentage score on the final exam than on the midterm exams, the final exam percentage will be used as a score for all three term exams. There is nothing to sign-up for. It is an automatic win-win situation. This is a mechanism which gives students who experienced educational difficulty during the term for any reason a chance to demonstrate that they have mastered the material and to profit from that mastery.
 

Final Exam Room Assignments
Tuesday, December 9, 2008 7:30-9:20AM
GOOD MORNING!
Click here to view a campus map

Last name begins with A-F ...your room is MLM 026 (MLM AUD)
Last name begins with G-I ...your room is WITH 109
Last name begins with J-L ...your room is PVY 130
Last name begins with M-Pa ...your room is WGND 115
Last name begins with Pe-Ra ...your room is COVL 221
Last name begins with Re-Ru ...your room is MLM 318
Last name begins with Sa-So ...your room is GLSN 200
Last name begins with Sp-To ...your room is ROG 230
Last name begins with Tr-Wal ...your room is PVY 242
Last name begins with Wan-X ...your room is WGND 106
Last name begins with Y-Z ...your room is GILB 324

 

http://winter.group.shef.ac.uk/orbitron/

 

 

 

Schrödinger Equation

 



where:

 

 

 

This is the form best suited for the study of the hydrogen atom.

 

 

       

 

The 20 greatest equations

 

 

 

 

 

 

 

 

 

 


 

Oil on Water

Such as:

http://en.wikipedia.org/wiki/Cosco_Busan

 

 

Values of R

Units
(V·P·T-1·n-1)

8.314472

J·K-1·mol-1

0.0820574587

L·atm·K-1·mol-1

83.14472

cm3·bar·mol-1·K-1

8.20574587 × 10-5

m3·atm·K-1·mol-1

8.314472

cm3·MPa·K-1·mol-1

8.314472

L·kPa·K-1·mol-1

8.314472

m3·Pa·K-1·mol-1

62.36367

mmHg·K-1·mol-1

62.36367

L·Torr·K-1·mol-1

83.14472

L·mbar·K-1·mol-1

0.08314472

L·bar·K-1·mol-1

1.987

cal·K-1·mol-1

6.132440

lbf·ft·K-1·g-mol-1

10.73159

ft3·psi· °R-1·lb-mol-1

0.7302413

ft3·atm·°R-1·lb-mol-1

998.9701

ft3·mmHg·K-1·lb-mol-1

8.314472 × 107

erg·K-1·mol-1

1716 (Air only)

ft·lb·°R-1·slug-1

286.9 (Air only)

N·m·kg-1·K-1

286.9 (Air only)

J·kg-1·K-1

from: http://en.wikipedia.org/wiki/Gas_constant



 

How Many? A Dictionary of Units of Measurement © Russ Rowlett and the University of North Carolina at Chapel Hill

The Metric System in the United States

Article I, Section 8 of the U. S. Constitution gives Congress the power to "fix the standard of weights and measures" for the nation. The First Congress, meeting in 1789, took up the question of weights and measures, and had the metric system been available at that time it might have been adopted. What actually happened is that Thomas Jefferson, who was then serving as the first Secretary of State, submitted a report proposing a decimal-based system with a mixture of familiar and unfamiliar names for the units.

Jefferson's system actually resembles the metric system in many ways. Its biggest shortcoming is that Jefferson didn't hit on the idea of using prefixes to create names for multiples of units. Consequently, his system was burdened with a long list of names. For example, he divided his basic distance unit, the foot (it was slightly shorter than the traditional foot) into 10 inches. Each inch was divided into 10 lines, and each line into 10 points. For larger distances, 10 feet equalled a decade, 100 feet was a rood, 1000 feet a furlong, and there were 10 000 feet in a mile (making the Jeffersonian mile about twice as long as the traditional mile). His basic volume unit was the cubic foot, which he proposed to call a bushel (it was about 3/4 the size of a traditional bushel). The basic weight unit was the ounce, defined so that a bushel of water weighed 1000 ounces. (This is very similar to the metric system, in which a liter of water weighs 1000 grams).

Congress gave this plan serious consideration, but because it lacked independent support from other scientists it was easy to criticize. Ultimately, Congress took no action. This left Americans with a version of the traditional English weights and measures, including:

It is remarkable that Congress never established this traditional system, or any other system, as the mandatory system of weights and measures for the United States. In 1832, Congress directed the Treasury Department to standardize the measures used by customs officials at U.S. ports. The Department adopted a report describing the traditional system, and Congress allowed this report to stand without taking any formal action. This is the closest the U.S. has ever come to adopting a single system of measurement. Ironically, the U.S. missed two opportunities in 1832. Americans could have adopted the metric system, which was then at an uncertain point in its history; or they could have decided to align their measurements with the British Imperial measures established by Parliament in 1824 and thus created a possible alternative to the metric system in international commerce.

 


 

 

October 6, 2008 Warm Up Exercise

Calcium is a ______________________ (metal or non-metal).  It is in Group Number _________.  Each calcium atom has ________ protons and

 

________ electrons.  Calcium can form an ionic compound (a salt) with nitrogen.  The name and formula of this compound are

 

______________________________ and ____________________________.  This compound is composed of calcium and nitride ions

 

(charged particles).  How many protons and electrons are in a calcium ion?  How many protons and electrons are in a nitride ion?

 

 

 


 

1 British thermal unit (Btu) = 1,055.05585262 joules (J)

1 calorie (cal) = 4.1868 joules (J)

1 kilowatthour (kWh) = 3.6 megajoules(MJ)

 

Nutrient Calories per gram
Carbohydrate 4 kcal
Protein 4 kcal
Fat 9 kcal
Alcohol 7 kcal

Table of specific heat capacities

Substance Phase cp
J g−1 K−1
Cp
J mol−1 K−1
Cv
J mol−1 K−1
Air (Sea level, dry, 0 °C) gas 1.0035 29.07  
Air (typical room conditionsA) gas 1.012 29.19  
Aluminium solid 0.897 24.2  
Ammonia liquid 4.700 80.08  
Antimony solid 0.207 25.2  
Argon gas 0.5203 20.7862 12.4717
Arsenic solid 0.328 24.6  
Beryllium solid 1.82 16.4  
Copper solid 0.385 24.47  
Diamond solid 0.5091 6.115  
Ethanol liquid 2.44 112  
Gasoline liquid 2.22 228  
Gold solid 0.1291 25.42  
Graphite solid 0.710 8.53  
Helium gas 5.1932 20.7862 12.4717
Hydrogen gas 14.30 28.82  
Iron solid 0.450 25.1  
Lead solid 0.127 26.4  
Lithium solid 3.58 24.8  
Magnesium solid 1.02 24.9  
Mercury liquid 0.1395 27.98  
Nitrogen gas 1.040 29.12 20.8
Neon gas 1.0301 20.7862 12.4717
Oxygen gas 0.918 29.38  
Paraffin wax solid 2.5 900  
Silica (fused) solid 0.703 42.2  
Uranium solid 0.116 27.7  
Water gas (100 °C) 2.080 37.47 28.03
liquid (25 °C) 4.1813 75.327 74.53
solid (0 °C) 2.114 38.09  
All measurements are at 25 °C unless otherwise noted.
Notable minima and maxima are shown in maroon.

http://en.wikipedia.org/wiki/Specific_heat

 

Oct 24, 2007    Two calculators were left in exam rooms last week.  A textbook was left in GILB 124 today.  Please see me before/after lecture to claim these items.

 

 

Oct 23, 2008 (Mole Day)

 

 

Boltzmann 3D Link

 

 

 

OWL Superscripts and Subscripts

For some answers, it is necessary to enter superscripts and subscripts in your answer. This is most frequently encountered with chemical formulas, mathematical equations, and units of measurement.
Enter subscripts between underscores (shift minus) and superscripts between carats (shift 6).

 

Examples

Value

Enter As

m/s2

m/s^2^

H2O

H_2_O

SO42-

SO_4_^2-^

Mg(NO3)2

Mg(NO_3_)^2^

 

When you submit an answer with a superscript or subscript in it, OWL allows you to view your answer to make sure that it is correct before it is graded.

 

The 9 polyatomic ions to know and write on your notecard:
Name Formula
Hydroxide OH-  
Cyanide CN-  
Nitrate NO3-  
Acetate CH3COO-  
Carbonate CO32-  
Phosphate PO43-  
Hydronium H3O+  
Ammonium NH4+
Sulfate SO42-  

 

Densities of Some Common Substances

Substance ... Density (g/mL)

 

Water 1.00

Aluminum 2.72

Chromium 7.25

Nickel 8.91

Copper 8.94

Silver 10.50

Lead 11.34

Mercury 13.60

Gold 19.28

Tungsten 19.38

Platinum 21.46

 

 

One day, Heisenberg was in his car speeding down the street and he was pulled over by a police officer.

The officer came up to the window and asked, "Heisenberg, do you have any idea how fast you were going?" Heisenberg answered, "No, but I know exactly where I am."

 

---

 

Relative Sizes

 

End of period

 

http://winter.group.shef.ac.uk/orbitron/

The following appears on the first two pages of Exam 2:

 

Chemistry 121                                      Fall 2006                                              Oregon State University

Exam 2                                     November 16, 2006                             Dr. Richard Nafshun

 

Instructions: You should have with you several number two pencils, an eraser, your 3" x 5" note card, a calculator, and your University ID Card.  If you have notes with you, place them in a sealed backpack and place the backpack OUT OF SIGHT or place the notes directly on the table at the front of the room.

 

Fill in the front page of the Scantron answer sheet with your test form number (listed above), last name, first name, middle initial, and student identification number.  Leave the class section number and the test form number blank.

 

This exam consists of 25 multiple-choice questions.  Each question has four points associated with it.  Select the best multiple-choice answer by filling in the corresponding circle on the rear page of the answer sheet.  If you have any questions before the exam, please ask.  If you have any questions during the exam, please ask the proctor.  Open and start this exam when instructed.  When finished, place your Scantron form and note card in the appropriate stacks.  You may keep the exam packet, so please show your work and mark the answers you selected on it.

 

Abbreviated Solubility Rules:

Rule 1:  All nitrates, group 1A metal salts and ammonium salts are soluble.

Rule 2:  All carbonates, hydroxides, phosphates and sulfides are insoluble.

Rule 3:  Rule 1 always takes precedent.

 

R = 0.0821

R = 8.314

PV = nRT

760 Torr = 1 atm = 760 mm Hg

K = 273.15 + °C

1 mole = 6.02 x 1023

milli (m) = 1/1000

kilo (k) = 1000

M1V1 = M2V2

MacidVacid = MbaseVbase

 

 

Hydroxide OH-

Cyanide CN-

Nitrate NO3-

Acetate CH3COO-

Carbonate CO32-

Phosphate PO43-

Hydronium H3O+

Ammonium NH4+

Sulfate SO42-

 

 

 

 

 

 

 

 

 

 

Periodic Table

of the

Elements Here

 

 

_____________________________________________________________________________________________________

 

Do you know what a wicket is? Have you ever seen someone playing a game with a bamboo ball and no hands? Do you like free food and fun? Come participate in a campus wide event, “Around the World in 4 Hours” Friday, November 17th from 10pm to 2am at the Dixon Recreation Center. We will have games, activities and food from all around the world. This event is sponsored by Dixon Recreation Center and coordinated by a new group on campus called, “After Hours”. Come learn more about how to get involved with late night programming on campus and join in on the fun. All students are welcome. We will hope to see you there.

 

 

 

 

 

The heat of fusion (ΔHfusion) of water is 79.72 calories per gram or 334.5 joules per gram.

 

            How much heat is required to change 100 g of ice at 0 °C to water at 25 °C?

 

 

                        ΔHfusion                                                           ΔHvaporization

 

Substance

Heat of fusion
(cal/g)

Heat of fusion
(J/g)

methane:

13.96

58.41

ethane:

22.73

95.10

propane:

19.11

79.96

methanol:

23.70

99.16

ethanol:

26.05

108.99

glycerol:

47.95

200.62

formic acid:

66.05

276.35

acetic acid:

45.91

192.09

acetone:

23.42

97.99

benzene:

30.45

127.40

myristic acid:

47.49

198.70

palmitic acid:

39.18

163.93

stearic acid:

47.54

198.91

Element

Heat of vaporization (kJ/mol)

Methanol

37.4

Ammonia

23.35

Water

40.65

Methane

8.19

Phosphine

14.6

Propane

356 kJ/kg

Butane

362 kJ/kg

 

 

 

 

 

 

Substance

Phase

cp
J g-1 K-1

Cp
J mol-1 K-1

Air (Sea level,dry,0°C)

gas

1.0035

29.07

Air (typical room conditions)

gas

1.012

29.19

Aluminum

solid

0.897

24.2

Ammonia

liquid

4.700

80.08

Argon

gas

0.5203

20.7862

Beryllium

solid

1.82

16.4

Copper

solid

0.385

24.47

Diamond

solid

0.5091

6.115

Ethanol

liquid

2.44

112

Gold

solid

0.1291

25.42

Graphite

solid

0.710

8.53

Helium

gas

5.1932

20.7862

Hydrogen

gas

14.30

28.82

Iron

solid

0.450

25.1

Lithium

solid

3.58

24.8

Mercury

liquid

0.1395

27.98

Nitrogen

gas

1.040

29.12

Neon

gas

1.0301

20.7862

Oxygen

gas

0.918

29.38

Silica (fused)

solid

0.703

42.2

Uranium

solid

0.116

27.7

Water

gas (100°C)

2.080

37.47

liquid (25°C)

4.1813

75.327

solid (0°C)

2.114

38.09

All measurements are at 25 °C unless otherwise noted.

Usually of interest to builders and solar designers

Substance

Phase

cp
J g-1 K-1

Asphalt

solid

0.92

Brick

solid

0.84

Concrete

solid

0.88

Glass, crown

solid

0.67

Glass, flint

solid

0.503

Glass, pyrex

solid

0.753

Granite

solid

0.790

Gypsum

solid

1.09

Marble, mica

solid

0.880

Sand

solid

0.835

Soil

solid

0.80

Wood

solid

0.42

 

 

Examples: Inorganic compounds (at 25 °C)

Chemical Compound Phase (matter) Chemical formula Δ Hf0 in kJ/mol
Ammonia aq NH3 -80.8
Ammonia g NH3 -46.1
Sodium carbonate s Na2CO3 -1131
Sodium chloride (table salt) aq NaCl -407
Sodium chloride (table salt) s NaCl -411.12
Sodium chloride (table salt) l NaCl -385.92
Sodium chloride (table salt) g NaCl -181.42
Sodium hydroxide aq NaOH -469.6
Sodium hydroxide s NaOH -426.7
Sodium nitrate aq NaNO3 -446.2
Sodium nitrate s NaNO3 -424.8
Sulphur dioxide g SO2 -297
Sulphuric acid l H2SO4 -814
Silica s SiO2 -911
Nitrogen dioxide g NO2 33
Nitrogen monoxide g NO 90
Water l H2O -286
Water g H2O -242
Hydrogen g H2 0
Fluorine g F2 0
Chlorine g Cl2 0
Bromine l Br2 0
Bromine g Br2 +31
Iodine s I2 0
Iodine g I2 +62
(State: g - gaseous; l - liquid; s - solid; aq = aqueous)

 

 

Compound DHf (kJ/mol) Compound DHf (kJ/mol)
AgBr(s)  -99.5  C2H2(g)  +226.7 
AgCl(s)  -127.0  C2H4(g)  +52.3 
AgI(s)  -62.4  C2H6(g)  -84.7 
Ag2O(s)  -30.6  C3H8(g)  -103.8 
Ag2S(s)  -31.8  n-C4H10(g)  -124.7 
Al2O3(s)  -1669.8  n-C5H12(l)  -173.1 
BaCl2(s)  -860.1  C2H5OH(l)  -277.6 
BaCO3(s)  -1218.8  CoO(s)  -239.3 
BaO(s)  -558.1  Cr2O3(s)  -1128.4 
BaSO4(s)  -1465.2  CuO(s)  -155.2 
CaCl2(s)  -795.0  Cu2O(s)  -166.7 
CaCO3  -1207.0  CuS(s)  -48.5 
CaO(s)  -635.5  CuSO4(s)  -769.9 
Ca(OH)2(s)  -986.6  Fe2O3(s)  -822.2 
CaSO4(s)  -1432.7  Fe3O4(s)  -1120.9 
CCl4(l)  -139.5  HBr(g)  -36.2 
CH4(g)  -74.8  HCl(g)  -92.3 
CHCl3(l)  -131.8  HF(g)  -268.6 
CH3OH(l)  -238.6  HI(g)  +25.9 
CO(g)  -110.5  HNO3(l)  -173.2 
CO2(g)  -393.5  H2O(g)  -241.8 
H2O(l)  -285.8  NH4Cl(s)  -315.4 
H2O2(l)  -187.6  NH4NO3(s)  -365.1 
H2S(g)  -20.1  NO(g)  +90.4 
H2SO4(l)  -811.3  NO2(g)  +33.9 
HgO(s)  -90.7  NiO(s)  -244.3 
HgS(s)  -58.2  PbBr2(s)  -277.0 
KBr(s)  -392.2  PbCl2(s)  -359.2 
KCl(s)  -435.9  PbO(s)  -217.9 
KClO3(s)  -391.4  PbO2(s)  -276.6 
KF(s)  -562.6  Pb3O4(s)  -734.7 
MgCl2(s)  -641.8  PCl3(g)  -306.4 
MgCO3(s)  -1113  PCl5(g)  -398.9 
MgO(s)  -601.8  SiO2(s)  -859.4 
Mg(OH)2(s)  -924.7  SnCl2(s)  -349.8 
MgSO4(s)  -1278.2  SnCl4(l)  -545.2 
MnO(s)  -384.9  SnO(s)  -286.2 
MnO2(s)  -519.7  SnO2(s)  -580.7 
NaCl(s)  -411.0  SO2(g)  -296.1 
NaF(s)  -569.0  So3(g)  -395.2 
NaOH(s)  -426.7  ZnO(s)  -348.0 
NH3(g)  -46.2  ZnS(s)  -202.9 

 

 

   

 

 

 

   

 

 

 

Salicylic acid

 

C7H6O3

 

 

 

Scientists Announce Creation of Atomic Element, the Heaviest Yet
 

By Rick Weiss
Washington Post Staff Writer
Tuesday, October 17, 2006; A03
 

 

Scientists in California and Russia announced yesterday that they have created the heaviest atomic element ever made, adding a new item to the universal menu of matter known as the periodic table and revealing fresh secrets about the nature of atoms, the fundamental units of physical stuff.

The new, radioactive element, which has not yet been formally named but is being referred to variously as ununoctium (Latin for "one-one-eight"), eka-radon (beneath radon on the periodic table) or simply element 118, did not linger long.

Indeed, as with most "super-heavy" elements -- which are not known to exist in nature but have been synthesized by slamming smaller atoms together -- the three atoms of ununoctium created in the latest experiments came and went in a literal flash.

But during their brief tenures of about nine ten-thousandths of a second each in a laboratory on Russia's Volga River, those three atoms revealed much about the laws that govern the behavior of matter, scientists said.

And while practical applications for such fleeting phenomena are difficult to envision, experts said they were confident some would appear -- especially if researchers can leverage the findings to make even larger atomic constructs that might have lifetimes of minutes, months or longer.

"One never knows what the application of the things you find may be," said Darleane Hoffman, a professor of chemistry at the University of California at Berkeley, tossing out the example of plutonium-239, the key fissile ingredient in atomic bombs, first created in 1941.

Physicists cautioned that the finding must be considered provisional for now. That is true of all experiments that have yet to be independently replicated, but especially so for the finding of element 118, whose discovery was first reported by a Berkeley team in 1999 and then retracted two years later when it became clear that the results were fraudulent.

The last new element to be confirmed was No. 111, roentgenium, discovered in 1994.

But scientists involved in the new find -- and others who reviewed the report, published in the October issue of the journal Physical Review C -- said they were virtually certain that what they saw in that millimoment was indeed a microhunk of ununoctium.

"I would say we're very confident," said team member Nancy Stoyer of the Lawrence Livermore National Laboratory in Livermore, Calif., estimating that the odds of the result being false were less than 1 in 10,000.

The team was led by Dawn Shaughnessy of Livermore and Yuri Oganessian of the Joint Institute for Nuclear Research in Dubna, Russia.

Every naturally occurring thing in the universe is made from a modest celestial palette of 92 elements, from hydrogen to uranium. Each element has an atomic number (from 1 to 92) representing the number of positively charged protons in that atom's core, or nucleus. Many variants, or isotopes, of each element also exist through the addition of varying numbers of uncharged neutrons to those nuclei.

For decades, scientists have been making new elements, heavier than any found in nature, in part to help them understand the basic forces that hold atoms together and keep them apart. They also want to know the biggest element that can be made. Theory predicts a finite limit.

The technique involves spraying a target made of one kind of atom with atomic buckshot of another kind and hoping that a few of the incoming nuclei will hit a few of the target atoms with enough force to overcome their mutually repulsive positive charges and merge into one giant nucleus, at least briefly. To accomplish that requires a combination of ultra-precise engineering and outlandish brute force.

In the latest experiments, which took more than 3,000 hours, the researchers fired about 40 billion billion atoms of calcium-48 -- a heavy, neutron-laden version of calcium -- at a target of californium-249, a highly radioactive synthetic element. Special sensors detected a total of three atoms of ununoctium flying off as a result of those painstaking efforts -- one in an experiment in 2002, and two in early 2005.

Each quickly threw off a pair of protons and a pair of neutrons to make element 116, then did so again to make element 114, and again to make element 112, which then split in two.

It is that trail of "daughters" that allows scientists to infer that a "mother" atom was there in the first place. But that kind of proof is tricky, said Walter Loveland, a chemistry professor at Oregon State University, because the super-heavy daughters are so poorly understood themselves.

Still, Loveland said he found the results "impressive and internally very self-consistent" and "a tremendous intellectual achievement."

One major question left unanswered by the experiment is whether there are super-heavy elements yet to be made that will be far more stable -- a predicted phenomenon that scientists have called "an island of stability."

An isotope of element 114, discovered by Livermore scientists, showed preliminary but now uncertain evidence of unusual longevity, on the order of 20 seconds. Some had predicted that ununoctium might stick around long enough for researchers to do some chemistry on it. The new work, while undermining that idea, offers new information that will help theoreticians revamp their predictions, which can then be tested by experimentalists.

"We're nibbling away at the shores of the island of stability," said Livermore's Ken Moody.

  

 

   

 

   

Darling,

 

Before you return from your trip I wanted to let you know about the small accident I had in the pick-up truck.  Fortunately I didn't get hurt, so please don't worry about me.  When I turned into the driveway I accidentally pushed down on the accelerator instead of the brake.  The garage door is slightly bent but fortunately the truck came to a halt when it bumped into your car.  I am really sorry but I know with your kind hearted personality you will forgive me.  You know how much I love you and care for you my sweetheart.  I cannot wait to hold you in my arms again.

 

Your loving spouse,

 

XXXOOO

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

   

 

 

    Metric Prefixes:

   

yotta- (Y-) 1024 1 septillion
zetta- (Z-) 1021 1 sextillion
exa- (E-) 1018 1 quintillion
peta- (P-) 1015 1 quadrillion
tera- (T-) 1012 1 trillion
giga- (G-) 109 1 billion
mega- (M-) 106 1 million
kilo- (k-) 103 1 thousand
hecto- (h-) 102 1 hundred
deka- (da-)** 10 1 ten
deci- (d-) 10-1 1 tenth
centi- (c-) 10-2 1 hundredth
milli- (m-) 10-3 1 thousandth
micro- (µ-) 10-6 1 millionth
nano- (n-) 10-9 1 billionth
pico- (p-) 10-12 1 trillionth
femto- (f-) 10-15 1 quadrillionth
atto- (a-) 10-18 1 quintillionth
zepto- (z-) 10-21 1 sextillionth
yocto- (y-) 10-24 1 septillionth

 

and...

 

1 ångström (Å) = 10–10 meters = 0.1 nm = 100 pm For an example of lengths in this unit, the average diameter of an atom, calculated from its empirical radius, ranges from approximately 0.5 Å for hydrogen (the smallest element) to 3.8 Å for uranium (the largest naturally occurring element on earth).

    Need more?  http://en.wikipedia.org/wiki/Conversion_of_units

 

 

    Polyatomic Ions:

The 9 polyatomic ions to know and write on your notecard:
Name Formula
Hydroxide OH-  
Cyanide CN-  
Nitrate NO3-  
Acetate CH3COO-  
Carbonate CO32-  
Phosphate PO43-  
Hydronium H3O+  
Ammonium NH4+
Sulfate SO42-  

   

Table of common polyatomic cations, arranged by family. Alternate names are given in italics.

carbon

nitrogen

sulfur

chlorine

 

 

CO32-

carbonate

 

 

 

 

 

 

HCO3-

hydrogen carbonate
(bicarbonate)

 

 

NO3-

nitrate

NO2-

nitrite

 

 

 

 

 

 

 

 

SO42-

sulfate

SO32-

sulfite

 

 

S2O32-

thiosulfate

HSO4-

hydrogen sulfate
(bisulfate)

HSO3-

hydrogen sulfite
(bisulfite)

ClO4-

perchlorate

ClO3-

chlorate

ClO2-

chlorite

ClO-

hypochlorite

 

phosphorus

cyanide

cations

metal oxyanions

PO43-

phosphate

HPO42-

hydrogen phosphate

H2PO4-

dihydrogen phosphate

CN-

cyanide

OCN-

cyanate

SCN-

thiocyanate

NH4+

ammonium

H3O+

hydronium

Hg22+

mercury(I)

CrO42-

chromate

Cr2O72-

dichromate

MnO4-

permanganate

 

oxygen

organics

OH-

hydroxide

O22-

peroxide

C2H3O2-

acetate

 

If you can remember the formula of the ion whose name ends with ate, you can usually work out the formulas of the other family members as follows:

modify stem name with:

meaning

examples

-ate

a common form, containing oxygen

chlorate, ClO3-
nitrate, NO3-
sulfate, SO42-

-ite

one less oxygen than -ate form

chlorite, ClO2-
sulfite, SO32-
nitrite, NO2-

per-, -ate

same charge, but contains one more oxygen than -ate form

perchlorate, ClO4-
perbromate, BrO4-

hypo-, -ite

same charge, but contains one less oxygen than the -ite form

hypochlorite, ClO- hypobromite, BrO-

thio-

replace an O with an S

thiosulfate, S2O32-
thiosulfite, S2O22-

Some anions can capture hydrogen ions. For example, carbonate (CO32- can capture an H+ to produce hydrogen carbonate HCO3- (often called bicarbonate). Each captured hydrogen neutralizes one minus charge on the anion.

modify stem name with:

meaning

examples

hydrogen
or bi-

(1) captured H+ ions

hydrogen carbonate, HCO3- (a.k.a. bicarbonate)
hydrogen sulfate, HSO4- (a.k.a. bisulfate)

dihydrogen

(2) captured H+ ions

dihydrogen phosphate, H2PO4-

Table of common polyatomic cations, arranged by charge. Alternate names are given in italics. Select the name of the ion for information about its occurrence, uses, properties, and structure.

+2

Hg22+

mercury(I) or mercurous

+1

NH4+

ammonium

H3O+

hydronium

-1

C2H3O2-

acetate

ClO3-

chlorate

ClO2-

chlorite

CN-

cyanide

H2PO4-

dihydrogen phosphate

HCO3-

hydrogen carbonate or bicarbonate

HSO4-

hydrogen sulfate or bisulfate

OH-

hydroxide

ClO-

hypochlorite

NO3-

nitrate

NO2-

nitrite

ClO4-

perchlorate

MnO4-

permanganate

SCN-

thiocyanate

-2

CO32-

carbonate

CrO42-

chromate

Cr2O72-

dichromate

HPO42-

hydrogen phosphate

O22-

peroxide

SO42-

sulfate

SO32-

sulfite

S2O32-

thiosulfate

-3

PO43-

phosphate

 

-1 CHARGE

-2 CHARGE

-3 CHARGE

-4 CHARGE

ion

name

ion

name

ion

name

ion

name

H2PO3-

dihydrogen phosphite

HPO32-

hydrogen phosphite

PO33-

phosphite

P2O74-

pyrophosphate

H2PO4-

dihydrogen phosphate

HPO42-

hydrogen phosphate

PO43-

phosphate

 

 

HCO3-

hydrogen carbonate

CO32-

carbonate

PO23-

hypophosphite

 

 

HSO3-

hydrogen sulfite

SO32-

sulfite

AsO33-

arsenite

 

 

HSO4-

hydrogen sulfate

SO42-

sulfate

AsO43-

arsenate

 

 

NO2-

nitrite

S2O32-

thiosulfate

 

 

 

 

NO3-

nitrate

SiO32-

silicate

 

 

 

 

OH-

hydroxide

C22-

carbide

 

 

 

 

CH3COO-

acetate

C2O42-

oxalate

 

 

 

 

CrO2-

chromite

CrO42-

chromate

 

 

 

 

CN-

cyanide

Cr2O72-

dichromate

 

 

 

 

CNO-

cyanate

C4H4O62-

tartrate

 

 

 

 

CNS-

thiocyanate

MoO42-

molybdate

 

 

 

 

O2-

superoxide

O22-

peroxide

 

 

 

 

MnO4-

permanganate

S22-

disulfide

 

 

 

 

ClO-

hypochlorite

 

 

 

 

 

 

ClO2-

chlorite

 

 

 

 

 

 

ClO3-

chlorate

 

 

 

 

 

 

ClO4-

perchlorate

 

 

 

 

 

 

BrO-

hypobromite

 

 

 

 

 

 

BrO2-

bromite

 

 

 

 

 

 

BrO3-

bromate

 

 

 

 

 

 

BrO4-

perbromate

 

 

 

 

 

 

IO-

hypoiodite

 

 

 

 

 

 

IO2-

iodite

 

 

 

 

 

 

IO3-

iodate

 

 

 

 

 

 

IO4-

periodate

 

 

 

 

 

 

AlO2-

aluminate

 

 

 

 

 

 

N3-

azide

 

 

 

 

 

 

 

 

 

 

 

Chemical & Engineering News Home

Newscripts October 31, 2005 Volume 83, Number 44 p. 52

Army Humvees Can Produce Water

Delivery of water to an army in the desert is a costly and time-consuming effort. The military calculates that a soldier in the desert needs 20 gal of water a day, five of which must be pure enough to drink. It can take up to 40% of troops deployed in the field just to transport water and other materials, so it would be a great advance if another source of water were available. That source might be vehicle exhaust. Engineers at United Technologies Corp.'s Hamilton Sundstrand unit are building two Humvees for the Army that will extract and clean water directly from the exhaust. Although the idea is not new, the Army has spent millions to make it work. The water vapor and other gases in the exhaust from the modified Humvees are vented through a catalytic converter to eliminate as many impurities as possible, and then run through a pair of heat exchangers to condense the water. This blackish liquid is then passed through a series of six proprietary carbon filters that bring the quality up to about tap water. Finally, chlorine is added to kill bacteria and algae, and the water flows into a 5-gal tank with a spigot. The water can be chilled by the Humvee's air conditioner. It is estimated that a vehicle could produce about 1 gal of water for each 2 gal of diesel fuel burned. The company recognizes that a lot of development still needs to be done. The system can cost more than 20% of the cost of the vehicle, it weighs almost 500 lb, and the water filters need to be changed every 75 to 200 gal. Still, if such a system can help soldiers survive if they cannot get other logistical support, it sounds like a good idea.

 

You might be from the Northwest if you...
Know the state flower (Mildew). 
Feel guilty throwing aluminum cans or paper in the trash. 
Use the statement "sun break" and know what it means. 
Know more than 10 ways to order coffee. 
Know more people who own boats than air conditioners. 
Feel overdressed wearing a suit to a nice restaurant. 
Stand on a deserted corner in the rain waiting for the "WALK" signal. 
Consider that if it has no snow or has not recently erupted, it is not a real mountain. 
Can taste the difference between Starbucks, Seattle's Best, and Veneto's. 
Know the difference between Chinook, Coho, and Sockeye salmon.
Know how to pronounce Sequim, Puyallup, Issaquah, Oregon, and Willamette.
Consider swimming an indoor sport.
In winter, go to work in the dark and come home in the dark, while only working eight-hour days. 
Never go camping without waterproof matches and a poncho. 
Are not fazed by "Today's forecast: showers followed by rain," and "Tomorrow's forecast: rain followed by showers." 
Cannot wait for a day with "showers and sun breaks." 
Have no concept of humidity without precipitation. 
Know that Boring is a town in Oregon and not just a state of mind. 
Can point to at least two volcanoes, even if you cannot see through the cloud cover. 
Notice "the mountain is out" when it is a pretty day and you can actually see it. 
Put on your shorts when the temperature gets above 50, but still wear your hiking boots and parka. 
Switch to your sandals when it gets about 60, but keep the socks on. 
Have actually used your mountain bike on a mountain. 
Think people who use umbrellas are either wimps or tourists. 
Knew immediately that the view out of Frasier's window was fake. 
Buy new sunglasses every year, because you can't find the old ones after such a long time. 
Measure distance in hours. 
Often switch from "heat" to "a/c" in the same day. 
Use a down comforter in the summer. 
Design your kid's Halloween costume to fit over a raincoat. 
Know all the important seasons: Almost Winter, Winter, Still Raining (Spring), Road Construction (Summer), Deer & Elk season (Fall). 
Actually understand these jokes and send them to all your friends in the northwest or those who used to live here! 

 

 

 

Tables of lots of polyatomic ions

 

The 9 polyatomic ions to know and write on your notecard:
Name Charge Formula
Hydroxide 1-   OH-  
Cyanide 1-   CN-  
Nitrate 1-   NO3-  
Acetate 1-   CH3COO-  
Carbonate 2- CO32-  
Phosphate 3-   PO43-  
Hydronium 1+ H3O+  
Ammonium 1+ NH4+
Sulfate 2-   SO42-  

 

Balancing reactions:

Trio shares Nobel prize for chemistry
Frenchman, 2 Americans honored for reducing hazardous chemical waste

The Associated Press
Updated: 6:11 a.m. ET Oct. 5, 2005

STOCKHOLM, Sweden - France's Yves Chauvin and Americans Robert H. Grubbs and Richard R. Schrock won the 2005 Nobel Prize in chemistry Wednesday, for their work to reduce hazardous waste in forming new chemicals.

The trio won the award for their development for the metathesis method in organic synthesis.

The Nobel Prize committee honored the laureates for their findings in metathesis, which focuses on how chemical bonds are broken and made between carbon atoms.

The process is used "daily in the chemical industry, mainly in the development of pharmaceuticals and advanced plastic materials."

"This represents a great step forward for 'green chemistry,' reducing potentially hazardous waste through smarter production. Metathesis is an example of how important basic science has been applied for the benefit of man, society and the environment," the committee said.

© 2005 The Associated Press.

 

Medal

The Nobel Prize in Chemistry 2005

"for the development of the metathesis method in organic synthesis"
 
Yves Chauvin Robert H. Grubbs Richard R. Schrock
Yves Chauvin Robert H. Grubbs Richard R. Schrock
third 1/3 of the prize third 1/3 of the prize third 1/3 of the prize
France USA USA
     
Institut Français du Pétrole
Rueil-Malmaison, France
California Institute of Technology (Caltech)
Pasadena, CA, USA
Massachusetts Institute of Technology (MIT)
Cambridge, MA, USA
b. 1930 b. 1942 b. 1945

http://nobelprize.org/

Medal

The Nobel Prize in Physics 2005

"for his contribution to the quantum theory of optical coherence" "for their contributions to the development of laser-based precision spectroscopy, including the optical frequency comb technique"
 
Roy J. Glauber John L. Hall Theodor W. Hänsch
Roy J. Glauber John L. Hall Theodor W. Hänsch
half 1/2 of the prize quarter 1/4 of the prize quarter 1/4 of the prize
USA USA Germany
     
Harvard University
Cambridge, MA, USA
University of Colorado, JILA; National Institute of Standards and Technology
Boulder, CO, USA
Max-Planck-Institut für Quantenoptik
Garching, Germany; Ludwig-Maximilians-Universität
Munich, Germany
b. 1925 b. 1934 b. 1941

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

Honda Designs Car Friendly for Dogs

 

For more upcoming events, go to http://oregonstate.edu/events/newsevents/events.html.

 

 

 

The text and solutions guide have been placed on reserve at the library:

# Title      Barcode   Call Num Author     Status Until      Location Checkouts
1 General    1201435386 VR 81    Ebbing;    Active 09-05-2006 vrbl     0
  Chemistry, 72                  Gammon                               
   8th ed                                                             
2 Solutions  1201435385 VR 82    Bookin,    Active 09-05-2006 vrbl     0
  Manual     73                  David                                
  for                                                                 
  General                                                             
  Chemistry,                                                          
   8th ed                    

Please inform your students that course reserves are filed by the call number or the VR number listed above.

 

SI prefixes
10n Prefix Symbol Short scale Long scale Decimal equivalent
1024 yotta Y Septillion Quadrillion 1 000 000 000 000 000 000 000 000
1021 zetta Z Sextillion Trilliard (thousand trillion) 1 000 000 000 000 000 000 000
1018 exa E Quintillion Trillion 1 000 000 000 000 000 000
1015 peta P Quadrillion Billiard (thousand billion) 1 000 000 000 000 000
1012 tera T Trillion Billion 1 000 000 000 000
109 giga G Billion Milliard (thousand million) 1 000 000 000
106 mega M Million 1 000 000
103 kilo k Thousand 1 000
102 hecto h Hundred 100
101 deca, deka da Ten 10
100 none none One 1
10−1 deci d Tenth 0.1
10−2 centi c Hundredth 0.01
10−3 milli m Thousandth 0.001
10−6 micro µ (u) Millionth 0.000 001
10−9 nano n Billionth Milliardth 0.000 000 001
10−12 pico p Trillionth Billionth 0.000 000 000 001
10−15 femto f Quadrillionth Billiardth 0.000 000 000 000 001
10−18 atto a Quintillionth Trillionth 0.000 000 000 000 000 001
10−21 zepto z Sextillionth Trilliardth 0.000 000 000 000 000 000 001
10−24 yocto y Septillionth Quadrillionth 0.000 000 000 000 000 000 000 001

 

Worksheet 1 will be discussed in recitation during Week 1.  A copy was provided during the first lecture meeting.  Click here to view/download.

The 9 polyatomic ions to know and write on your notecard:
Name Formula
Hydroxide OH-  
Cyanide CN-  
Nitrate NO3-  
Acetate CH3COO-  
Carbonate CO32-  
Phosphate PO43-  
Hydronium H3O+  
Ammonium NH4+
Sulfate SO42-  

 

Exam 1 Study Tips:
Worksheets
Past Exams
Notes
ChemSkill Builder
Study in small groups


Sample Standard Enthalpies of Formation Table--See Table 6.2 in your text:

Study Tips:

Worksheets

Past Exams

Notes

Final Exam Room Assignments
Tuesday, December 9, 2008 7:20-9:30AM
GOOD MORNING!
Click here to view a campus map

Last name begins with A-Ch ...your room is CORD 1109
Last name begins with Cl-E ...your room is COVL 216
Last name begins with F-I ...your room is GLFN AUD
(GLFN AUD is not listed on the campus map--it is north of WLKN and connected by an overhang)
Last name begins with J-Ma ...your room is GILB 124
Last name begins with Mc-Q ...your room is GILB 224
Last name begins with R-Sm ...your room is PVY 130
Last name begins with So-U ...your room is PHAR 305
Last name begins with V-Z ...your room is DEAR 118