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The 2008 CH 121 final exam cover sheet is
identical to the 2007 final exam cover sheet. Our CH 121 final exam is
scheduled for 7:30am on Tuesday, December 9, 2008. The exam period is from
7:30-9:20am (Good Morning!). The exam is approximately 40 questions. About 1/3
of the questions cover the Exam 1 objectives (read as: similar to Exam 1
questions). About 1/3 of the questions cover the Exam 2 objectives (read as:
similar to Exam 2 questions). About 1/3 of the questions cover the Quantum
objectives (our material from Chapter 7 and part of Chapter 8). Students have
found it valuable to print out and retake Exam 1 from October and Exam 2 from
November. These and the keys are still available from the Exams
Information link (http://www.chem.orst.edu/courses/ch121-3/ch121/ch121examinformation/ch121exam.htm).
Check your solutions and brush up on these concepts. To study for the last
third of the exam, practice past final exams (http://www.chem.orst.edu/courses/ch121-3/ch121/ch121examinformation/ch121exam.htm),
complete OWLs, complete Worksheets, and discuss concepts.
Many students significantly increase their course standing with a tremendous
final exam score. The exam policy is:
If you write a higher percentage score on the final exam than on the midterm
exams, the final exam percentage will be used as a score for all three term
exams. There is nothing to sign-up for. It is an automatic win-win situation.
This is a mechanism which gives students who experienced educational
difficulty during the term for any reason a chance to demonstrate that they
have mastered the material and to profit from that mastery.
|
Final
Exam Room Assignments
Tuesday, December 9, 2008 7:30-9:20AM
GOOD MORNING!
Click here to view a campus map |
|
Last name begins with A-F |
...your room is MLM 026 (MLM AUD) |
|
Last name begins with G-I |
...your room is WITH 109 |
|
Last name begins with J-L |
...your room is
PVY 130 |
|
Last name begins with M-Pa |
...your room is WGND 115 |
|
Last name begins with Pe-Ra |
...your room is COVL 221 |
|
Last name begins with Re-Ru |
...your room is
MLM 318 |
|
Last name begins with Sa-So |
...your room is GLSN 200 |
|
Last name begins with Sp-To |
...your room is ROG 230 |
|
Last name begins with Tr-Wal |
...your room is PVY 242 |
|
Last name begins with Wan-X |
...your room is WGND 106 |
|
Last name begins with Y-Z |
...your room is GILB 324 |
http://winter.group.shef.ac.uk/orbitron/
Schrödinger Equation

where:

This is the form
best suited for the study of the hydrogen atom.












Oil on Water
Such as:
http://en.wikipedia.org/wiki/Cosco_Busan
|
Values of R |
Units
(V·P·T-1·n-1) |
|
8.314472 |
J·K-1·mol-1 |
|
0.0820574587 |
L·atm·K-1·mol-1 |
|
83.14472 |
cm3·bar·mol-1·K-1 |
|
8.20574587 × 10-5 |
m3·atm·K-1·mol-1 |
|
8.314472 |
cm3·MPa·K-1·mol-1 |
|
8.314472 |
L·kPa·K-1·mol-1 |
|
8.314472 |
m3·Pa·K-1·mol-1 |
|
62.36367 |
L·mmHg·K-1·mol-1 |
|
62.36367 |
L·Torr·K-1·mol-1 |
|
83.14472 |
L·mbar·K-1·mol-1 |
|
0.08314472 |
L·bar·K-1·mol-1 |
|
1.987 |
cal·K-1·mol-1 |
|
6.132440 |
lbf·ft·K-1·g-mol-1 |
|
10.73159 |
ft3·psi·
°R-1·lb-mol-1 |
|
0.7302413 |
ft3·atm·°R-1·lb-mol-1 |
|
998.9701 |
ft3·mmHg·K-1·lb-mol-1 |
|
8.314472 × 107 |
erg·K-1·mol-1 |
|
1716 (Air only) |
ft·lb·°R-1·slug-1 |
|
286.9 (Air only) |
N·m·kg-1·K-1 |
|
286.9 (Air only) |
J·kg-1·K-1 |
from: http://en.wikipedia.org/wiki/Gas_constant
How Many? A Dictionary of Units of Measurement © Russ
Rowlett and the University of North Carolina at Chapel Hill
The Metric System in the United States
Article I, Section 8 of the U. S. Constitution gives Congress the power to
"fix the standard of weights and measures" for the nation. The First Congress,
meeting in 1789, took up the question of weights and measures, and had the
metric system been available at that time it might have been adopted. What
actually happened is that Thomas Jefferson, who was then serving as the first
Secretary of State, submitted a report proposing a decimal-based system with a
mixture of familiar and unfamiliar names for the units.
Jefferson's system actually resembles the metric system in many ways. Its
biggest shortcoming is that Jefferson didn't hit on the idea of using prefixes
to create names for multiples of units. Consequently, his system was burdened
with a long list of names. For example, he divided his basic distance unit,
the foot (it was slightly shorter than the traditional foot) into 10 inches.
Each inch was divided into 10 lines, and each line into 10 points. For larger
distances, 10 feet equalled a decade, 100 feet was a rood, 1000 feet a
furlong, and there were 10 000 feet in a mile (making the Jeffersonian mile
about twice as long as the traditional mile). His basic volume unit was the
cubic foot, which he proposed to call a bushel (it was about 3/4 the size of a
traditional bushel). The basic weight unit was the ounce, defined so that a
bushel of water weighed 1000 ounces. (This is very similar to the metric
system, in which a liter of water weighs 1000 grams).
Congress gave this plan serious consideration, but because it lacked
independent support from other scientists it was easy to criticize.
Ultimately, Congress took no action. This left Americans with a version of the
traditional English weights and measures, including:
- distance measurements identical to those of the 1592 Act of Parliament,
- the traditional avoirdupois system of weight measurements,
- a system of measurement for dry volumes based on the "Winchester" bushel
used in England for wheat and corn since the late Middle Ages, and
- a system of measurement for liquid volumes based on the English wine
gallon of 1707.
It is remarkable that Congress never established this traditional system,
or any other system, as the mandatory system of weights and measures for the
United States. In 1832, Congress directed the Treasury Department to
standardize the measures used by customs officials at U.S. ports. The
Department adopted a report describing the traditional system, and Congress
allowed this report to stand without taking any formal action. This is the
closest the U.S. has ever come to adopting a single system of measurement.
Ironically, the U.S. missed two opportunities in 1832. Americans could have
adopted the metric system, which was then at an uncertain point in its
history; or they could have decided to align their measurements with the
British Imperial measures established by Parliament in 1824 and thus created a
possible alternative to the metric system in international commerce.
October 6, 2008 Warm Up Exercise

Calcium is a
______________________ (metal or non-metal). It is in Group Number
_________. Each calcium atom has ________ protons and
________ electrons.
Calcium can form an ionic compound (a salt) with nitrogen. The name and
formula of this compound are
______________________________
and ____________________________. This compound is composed of calcium
and nitride ions
(charged particles). How
many protons and electrons are in a calcium ion? How many protons and
electrons are in a nitride ion?
1 British thermal unit (Btu) = 1,055.05585262 joules (J)
1 calorie (cal) = 4.1868 joules (J)
1 kilowatthour (kWh) = 3.6 megajoules(MJ)
| Nutrient |
Calories per gram |
| Carbohydrate |
4 kcal |
| Protein |
4 kcal |
| Fat |
9 kcal |
| Alcohol |
7 kcal |
Table of specific heat capacities
| Substance |
Phase |
cp
J g−1 K−1 |
Cp
J mol−1 K−1 |
Cv
J mol−1 K−1 |
|
Air (Sea level, dry, 0 °C) |
gas |
1.0035 |
29.07 |
|
| Air (typical room conditionsA) |
gas |
1.012 |
29.19 |
|
|
Aluminium |
solid |
0.897 |
24.2 |
|
| Ammonia |
liquid |
4.700 |
80.08 |
|
|
Antimony |
solid |
0.207 |
25.2 |
|
| Argon |
gas |
0.5203 |
20.7862 |
12.4717 |
| Arsenic |
solid |
0.328 |
24.6 |
|
|
Beryllium |
solid |
1.82 |
16.4 |
|
| Copper |
solid |
0.385 |
24.47 |
|
| Diamond |
solid |
0.5091 |
6.115 |
|
| Ethanol |
liquid |
2.44 |
112 |
|
|
Gasoline |
liquid |
2.22 |
228 |
|
| Gold |
solid |
0.1291 |
25.42 |
|
|
Graphite |
solid |
0.710 |
8.53 |
|
| Helium |
gas |
5.1932 |
20.7862 |
12.4717 |
|
Hydrogen |
gas |
14.30 |
28.82 |
|
| Iron |
solid |
0.450 |
25.1 |
|
| Lead |
solid |
0.127 |
26.4 |
|
| Lithium |
solid |
3.58 |
24.8 |
|
|
Magnesium |
solid |
1.02 |
24.9 |
|
|
Mercury |
liquid |
0.1395 |
27.98 |
|
|
Nitrogen |
gas |
1.040 |
29.12 |
20.8 |
| Neon |
gas |
1.0301 |
20.7862 |
12.4717 |
| Oxygen |
gas |
0.918 |
29.38 |
|
|
Paraffin wax |
solid |
2.5 |
900 |
|
|
Silica (fused) |
solid |
0.703 |
42.2 |
|
| Uranium |
solid |
0.116 |
27.7 |
|
|
Water |
gas (100 °C) |
2.080 |
37.47 |
28.03 |
| liquid (25 °C) |
4.1813 |
75.327 |
74.53 |
| solid (0 °C) |
2.114 |
38.09 |
|
All
measurements are at 25 °C unless otherwise noted.
Notable minima and maxima are shown in maroon.
http://en.wikipedia.org/wiki/Specific_heat |
Oct 24, 2007 Two calculators were left in
exam rooms last week. A textbook was left in GILB 124 today.
Please see me before/after lecture to claim these items.


Oct 23, 2008 (Mole Day)

Boltzmann 3D Link

OWL
Superscripts and Subscripts
For some answers,
it is necessary to enter superscripts and subscripts in your answer. This is
most frequently encountered with chemical formulas, mathematical equations,
and units of measurement.
Enter subscripts between underscores (shift minus) and superscripts between
carats (shift 6).
Examples
|
Value |
Enter As |
|
m/s2 |
m/s^2^ |
|
H2O |
H_2_O |
|
SO42- |
SO_4_^2-^ |
|
Mg(NO3)2 |
Mg(NO_3_)^2^ |
When you submit
an answer with a superscript or subscript in it, OWL allows you to
view
your answer to make sure that it is correct before it is graded.
| The 9
polyatomic ions to know and write on your notecard: |
| Name
|
Formula
|
| Hydroxide
|
OH- |
| Cyanide
|
CN- |
| Nitrate
|
NO3-
|
| Acetate
|
CH3COO-
|
| Carbonate
|
CO32-
|
| Phosphate
|
PO43-
|
| Hydronium
|
H3O+
|
| Ammonium
|
NH4+ |
| Sulfate
|
SO42-
|
Densities of
Some Common Substances
Substance ...
Density (g/mL)
Water 1.00
Aluminum 2.72
Chromium 7.25
Nickel 8.91
Copper 8.94
Silver 10.50
Lead 11.34
Mercury 13.60
Gold 19.28
Tungsten 19.38
Platinum 21.46
One day, Heisenberg was in his car speeding down the street
and he was pulled over by a police officer.
The officer came up to the window and asked, "Heisenberg, do
you have any idea how fast you were going?" Heisenberg answered, "No, but I
know exactly where I am."
---
Relative Sizes
End of period
http://winter.group.shef.ac.uk/orbitron/
The following appears on the first two pages of Exam 2:
Chemistry 121 Fall
2006 Oregon State University
Exam 2 November 16,
2006 Dr. Richard Nafshun
Instructions: You should have with you several number two
pencils, an eraser, your 3" x 5" note card, a calculator, and your University
ID Card. If you have notes with you, place them in a sealed backpack and
place the backpack OUT OF SIGHT or place the notes directly on the table at
the front of the room.
Fill in the front page of the Scantron answer sheet with
your test form number (listed above), last name, first name, middle initial,
and student identification number. Leave the class section number and the
test form number blank.
This exam consists of 25 multiple-choice questions. Each
question has four points associated with it. Select the best multiple-choice
answer by filling in the corresponding circle on the rear page of the answer
sheet. If you have any questions before the exam, please ask. If you have
any questions during the exam, please ask the proctor. Open and start this
exam when instructed. When finished, place your Scantron form and note card
in the appropriate stacks. You may keep the exam packet, so please show your
work and mark the answers you selected on it.
|
Abbreviated Solubility Rules:
Rule 1: All nitrates,
group 1A metal salts and ammonium salts are soluble.
Rule 2: All carbonates,
hydroxides, phosphates and sulfides are insoluble.
Rule 3: Rule 1 always
takes precedent. |
|
R = 0.0821
 |
R = 8.314
 |
 |
|
PV = nRT |
760 Torr = 1
atm = 760 mm Hg |
K = 273.15 +
°C |
|
1 mole =
6.02 x 1023 |
 |
milli (m) = 1/1000
kilo (k) = 1000 |
|
M1V1
= M2V2 |
MacidVacid = MbaseVbase |
|
|
Hydroxide OH- |
Cyanide CN- |
Nitrate NO3- |
|
Acetate CH3COO- |
Carbonate CO32- |
Phosphate PO43- |
|
Hydronium H3O+ |
Ammonium NH4+ |
Sulfate SO42- |


Periodic Table
of the
Elements Here
_____________________________________________________________________________________________________
Do you know what a wicket is?
Have you ever seen someone playing a game with a bamboo ball and no hands? Do
you like free food and fun? Come participate in a campus wide event, “Around
the World in 4 Hours” Friday, November 17th from 10pm to 2am at the Dixon
Recreation Center. We will have games, activities and food from all around the
world. This event is sponsored by Dixon Recreation Center and coordinated by a
new group on campus called, “After Hours”. Come learn more about how to get
involved with late night programming on campus and join in on the fun. All
students are welcome. We will hope to see you there.


The heat of fusion (ΔHfusion) of water is
79.72 calories per gram or 334.5 joules per gram.
How much heat is required to change 100 g of
ice at 0 °C to water at 25 °C?
ΔHfusion
ΔHvaporization
|
Substance |
Heat of fusion
(cal/g) |
Heat of fusion
(J/g) |
|
methane: |
13.96 |
58.41 |
|
ethane: |
22.73 |
95.10 |
|
propane: |
19.11 |
79.96 |
|
methanol: |
23.70 |
99.16 |
|
ethanol: |
26.05 |
108.99 |
|
glycerol: |
47.95 |
200.62 |
|
formic acid: |
66.05 |
276.35 |
|
acetic acid: |
45.91 |
192.09 |
|
acetone: |
23.42 |
97.99 |
|
benzene: |
30.45 |
127.40 |
|
myristic acid: |
47.49 |
198.70 |
|
palmitic acid: |
39.18 |
163.93 |
|
stearic acid: |
47.54 |
198.91 |
|
|
Element |
Heat of
vaporization (kJ/mol) |
|
Methanol |
37.4 |
|
Ammonia |
23.35 |
|
Water |
40.65 |
|
Methane |
8.19 |
|
Phosphine |
14.6 |
|
Propane |
356 kJ/kg |
|
Butane |
362 kJ/kg |
|
|
|
Substance |
Phase |
cp
J g-1 K-1 |
Cp
J mol-1 K-1 |
|
Air (Sea
level,dry,0°C) |
gas |
1.0035 |
29.07 |
|
Air (typical room
conditions) |
gas |
1.012 |
29.19 |
|
Aluminum |
solid |
0.897 |
24.2 |
|
Ammonia |
liquid |
4.700 |
80.08 |
|
Argon |
gas |
0.5203 |
20.7862 |
|
Beryllium |
solid |
1.82 |
16.4 |
|
Copper |
solid |
0.385 |
24.47 |
|
Diamond |
solid |
0.5091 |
6.115 |
|
Ethanol |
liquid |
2.44 |
112 |
|
Gold |
solid |
0.1291 |
25.42 |
|
Graphite |
solid |
0.710 |
8.53 |
|
Helium |
gas |
5.1932 |
20.7862 |
|
Hydrogen |
gas |
14.30 |
28.82 |
|
Iron |
solid |
0.450 |
25.1 |
|
Lithium |
solid |
3.58 |
24.8 |
|
Mercury |
liquid |
0.1395 |
27.98 |
|
Nitrogen |
gas |
1.040 |
29.12 |
|
Neon |
gas |
1.0301 |
20.7862 |
|
Oxygen |
gas |
0.918 |
29.38 |
|
Silica (fused) |
solid |
0.703 |
42.2 |
|
Uranium |
solid |
0.116 |
27.7 |
|
Water |
gas (100°C) |
2.080 |
37.47 |
|
liquid (25°C) |
4.1813 |
75.327 |
|
solid (0°C) |
2.114 |
38.09 |
|
All measurements
are at 25 °C unless otherwise noted. |
|
Usually of interest to
builders and solar designers
|
Substance |
Phase |
cp
J g-1 K-1 |
|
Asphalt |
solid |
0.92 |
|
Brick |
solid |
0.84 |
|
Concrete |
solid |
0.88 |
|
Glass, crown |
solid |
0.67 |
|
Glass, flint |
solid |
0.503 |
|
Glass, pyrex |
solid |
0.753 |
|
Granite |
solid |
0.790 |
|
Gypsum |
solid |
1.09 |
|
Marble, mica |
solid |
0.880 |
|
Sand |
solid |
0.835 |
|
Soil |
solid |
0.80 |
|
Wood |
solid |
0.42 |
|
Examples: Inorganic compounds (at 25 °C)
- (State: g - gaseous; l - liquid; s - solid; aq = aqueous)
| Compound
|
DHf (kJ/mol) |
Compound
|
DHf (kJ/mol) |
| AgBr(s) |
-99.5 |
C2H2(g) |
+226.7 |
| AgCl(s) |
-127.0 |
C2H4(g) |
+52.3 |
| AgI(s) |
-62.4 |
C2H6(g) |
-84.7 |
| Ag2O(s) |
-30.6 |
C3H8(g) |
-103.8 |
| Ag2S(s) |
-31.8 |
n-C4H10(g) |
-124.7 |
| Al2O3(s) |
-1669.8 |
n-C5H12(l) |
-173.1 |
| BaCl2(s) |
-860.1 |
C2H5OH(l) |
-277.6 |
| BaCO3(s) |
-1218.8 |
CoO(s) |
-239.3 |
| BaO(s) |
-558.1 |
Cr2O3(s) |
-1128.4 |
| BaSO4(s) |
-1465.2 |
CuO(s) |
-155.2 |
| CaCl2(s) |
-795.0 |
Cu2O(s) |
-166.7 |
| CaCO3 |
-1207.0 |
CuS(s) |
-48.5 |
| CaO(s) |
-635.5 |
CuSO4(s) |
-769.9 |
| Ca(OH)2(s) |
-986.6 |
Fe2O3(s) |
-822.2 |
| CaSO4(s) |
-1432.7 |
Fe3O4(s) |
-1120.9 |
| CCl4(l) |
-139.5 |
HBr(g) |
-36.2 |
| CH4(g) |
-74.8 |
HCl(g) |
-92.3 |
| CHCl3(l) |
-131.8 |
HF(g) |
-268.6 |
| CH3OH(l) |
-238.6 |
HI(g) |
+25.9 |
| CO(g) |
-110.5 |
HNO3(l) |
-173.2 |
| CO2(g) |
-393.5 |
H2O(g) |
-241.8 |
| H2O(l) |
-285.8 |
NH4Cl(s) |
-315.4 |
| H2O2(l) |
-187.6 |
NH4NO3(s) |
-365.1 |
| H2S(g) |
-20.1 |
NO(g) |
+90.4 |
| H2SO4(l) |
-811.3 |
NO2(g) |
+33.9 |
| HgO(s) |
-90.7 |
NiO(s) |
-244.3 |
| HgS(s) |
-58.2 |
PbBr2(s) |
-277.0 |
| KBr(s) |
-392.2 |
PbCl2(s) |
-359.2 |
| KCl(s) |
-435.9 |
PbO(s) |
-217.9 |
| KClO3(s) |
-391.4 |
PbO2(s) |
-276.6 |
| KF(s) |
-562.6 |
Pb3O4(s) |
-734.7 |
| MgCl2(s) |
-641.8 |
PCl3(g) |
-306.4 |
| MgCO3(s) |
-1113 |
PCl5(g) |
-398.9 |
| MgO(s) |
-601.8 |
SiO2(s) |
-859.4 |
| Mg(OH)2(s) |
-924.7 |
SnCl2(s) |
-349.8 |
| MgSO4(s) |
-1278.2 |
SnCl4(l) |
-545.2 |
| MnO(s) |
-384.9 |
SnO(s) |
-286.2 |
| MnO2(s) |
-519.7 |
SnO2(s) |
-580.7 |
| NaCl(s) |
-411.0 |
SO2(g) |
-296.1 |
| NaF(s) |
-569.0 |
So3(g) |
-395.2 |
| NaOH(s) |
-426.7 |
ZnO(s) |
-348.0 |
| NH3(g) |
-46.2 |
ZnS(s) |
-202.9 |
Salicylic acid

C7H6O3


Scientists Announce Creation of Atomic
Element, the Heaviest Yet
By Rick Weiss
Washington Post Staff Writer
Tuesday, October 17, 2006; A03
Scientists in California and Russia announced yesterday that
they have created the heaviest atomic element ever made, adding a new item
to the universal menu of matter known as the periodic table and revealing
fresh secrets about the nature of atoms, the fundamental units of physical
stuff.
The new, radioactive element, which has not yet been
formally named but is being referred to variously as ununoctium (Latin for
"one-one-eight"), eka-radon (beneath radon on the periodic table) or simply
element 118, did not linger long.
Indeed, as with most "super-heavy" elements -- which are not
known to exist in nature but have been synthesized by slamming smaller atoms
together -- the three atoms of ununoctium created in the latest experiments
came and went in a literal flash.
But during their brief tenures of about nine ten-thousandths
of a second each in a laboratory on Russia's Volga River, those three atoms
revealed much about the laws that govern the behavior of matter, scientists
said.
And while practical applications for such fleeting phenomena
are difficult to envision, experts said they were confident some would
appear -- especially if researchers can leverage the findings to make even
larger atomic constructs that might have lifetimes of minutes, months or
longer.
"One never knows what the application of the things you find
may be," said Darleane Hoffman, a professor of chemistry at the University
of California at Berkeley, tossing out the example of plutonium-239, the key
fissile ingredient in atomic bombs, first created in 1941.
Physicists cautioned that the finding must be considered
provisional for now. That is true of all experiments that have yet to be
independently replicated, but especially so for the finding of element 118,
whose discovery was first reported by a Berkeley team in 1999 and then
retracted two years later when it became clear that the results were
fraudulent.
The last new element to be confirmed was No. 111,
roentgenium, discovered in 1994.
But scientists involved in the new find -- and others who
reviewed the report, published in the October issue of the journal Physical
Review C -- said they were virtually certain that what they saw in that
millimoment was indeed a microhunk of ununoctium.
"I would say we're very confident," said team member Nancy
Stoyer of the Lawrence Livermore National Laboratory in Livermore, Calif.,
estimating that the odds of the result being false were less than 1 in
10,000.
The team was led by Dawn Shaughnessy of Livermore and Yuri
Oganessian of the Joint Institute for Nuclear Research in Dubna, Russia.
Every naturally occurring thing in the universe is made from
a modest celestial palette of 92 elements, from hydrogen to uranium. Each
element has an atomic number (from 1 to 92) representing the number of
positively charged protons in that atom's core, or nucleus. Many variants,
or isotopes, of each element also exist through the addition of varying
numbers of uncharged neutrons to those nuclei.
For decades, scientists have been making new elements,
heavier than any found in nature, in part to help them understand the basic
forces that hold atoms together and keep them apart. They also want to know
the biggest element that can be made. Theory predicts a finite limit.
The technique involves spraying a target made of one kind of
atom with atomic buckshot of another kind and hoping that a few of the
incoming nuclei will hit a few of the target atoms with enough force to
overcome their mutually repulsive positive charges and merge into one giant
nucleus, at least briefly. To accomplish that requires a combination of
ultra-precise engineering and outlandish brute force.
In the latest experiments, which took more than 3,000 hours,
the researchers fired about 40 billion billion atoms of calcium-48 -- a
heavy, neutron-laden version of calcium -- at a target of californium-249, a
highly radioactive synthetic element. Special sensors detected a total of
three atoms of ununoctium flying off as a result of those painstaking
efforts -- one in an experiment in 2002, and two in early 2005.
Each quickly threw off a pair of protons and a pair of
neutrons to make element 116, then did so again to make element 114, and
again to make element 112, which then split in two.
It is that trail of "daughters" that allows scientists to
infer that a "mother" atom was there in the first place. But that kind of
proof is tricky, said Walter Loveland, a chemistry professor at Oregon State
University, because the super-heavy daughters are so poorly understood
themselves.
Still, Loveland said he found the results "impressive and
internally very self-consistent" and "a tremendous intellectual
achievement."
One major question left unanswered by the experiment is
whether there are super-heavy elements yet to be made that will be far more
stable -- a predicted phenomenon that scientists have called "an island of
stability."
An isotope of element 114, discovered by Livermore
scientists, showed preliminary but now uncertain evidence of unusual
longevity, on the order of 20 seconds. Some had predicted that ununoctium
might stick around long enough for researchers to do some chemistry on it.
The new work, while undermining that idea, offers new information that will
help theoreticians revamp their predictions, which can then be tested by
experimentalists.
"We're nibbling away at the shores of the island of
stability," said Livermore's Ken Moody.
Darling,
Before you
return from your trip I wanted to let you know about the small accident I
had in the pick-up truck. Fortunately I didn't get hurt, so please
don't worry about me. When I turned into the driveway I accidentally
pushed down on the accelerator instead of the brake. The garage door is
slightly bent but fortunately the truck came to a halt when it bumped into
your car. I am really sorry but I know with your kind hearted
personality you will forgive me. You know how much I love you and care
for you my sweetheart. I cannot wait to hold you in my arms again.
Your loving
spouse,
XXXOOO

Metric Prefixes:
| yotta- (Y-) |
1024 |
1 septillion |
| zetta- (Z-) |
1021 |
1 sextillion |
| exa- (E-) |
1018 |
1 quintillion |
| peta- (P-) |
1015 |
1 quadrillion |
| tera- (T-) |
1012 |
1 trillion |
| giga- (G-) |
109 |
1 billion |
| mega- (M-) |
106 |
1 million |
| kilo- (k-) |
103 |
1 thousand |
| hecto- (h-) |
102 |
1 hundred |
| deka- (da-)** |
10 |
1 ten |
| deci- (d-) |
10-1 |
1 tenth |
| centi- (c-) |
10-2 |
1 hundredth |
| milli- (m-) |
10-3 |
1 thousandth |
| micro- (µ-) |
10-6 |
1 millionth |
| nano- (n-) |
10-9 |
1 billionth |
| pico- (p-) |
10-12 |
1 trillionth |
| femto- (f-) |
10-15 |
1 quadrillionth |
| atto- (a-) |
10-18 |
1 quintillionth |
| zepto- (z-) |
10-21 |
1 sextillionth |
| yocto- (y-) |
10-24 |
1 septillionth |
and...
1 ångström (Å) = 10–10 meters = 0.1 nm = 100
pm For an example of lengths in this unit, the average diameter of an atom,
calculated from its empirical radius, ranges from approximately 0.5 Å for
hydrogen (the smallest element) to 3.8 Å for uranium (the largest naturally
occurring element on earth).
Need more?
http://en.wikipedia.org/wiki/Conversion_of_units
Polyatomic Ions:
| The 9 polyatomic ions to know and write on your notecard: |
| Name |
Formula |
| Hydroxide |
OH- |
| Cyanide |
CN- |
| Nitrate |
NO3- |
| Acetate |
CH3COO- |
| Carbonate |
CO32- |
| Phosphate |
PO43- |
| Hydronium |
H3O+ |
| Ammonium |
NH4+ |
| Sulfate |
SO42- |
Table of common
polyatomic cations, arranged by family. Alternate names are given in italics.
|
carbon |
nitrogen |
sulfur |
chlorine |
|
|
|
|
CO32- |
carbonate |
|
|
|
|
|
|
|
|
|
|
HCO3- |
hydrogen carbonate
(bicarbonate) |
|
|
|
|
|
|
SO42- |
sulfate |
|
SO32- |
sulfite |
|
|
|
|
S2O32- |
thiosulfate |
|
HSO4- |
hydrogen sulfate
(bisulfate) |
|
HSO3- |
hydrogen sulfite
(bisulfite) |
|
|
ClO4- |
perchlorate |
|
ClO3- |
chlorate |
|
ClO2- |
chlorite |
|
ClO- |
hypochlorite |
|
|
phosphorus |
cyanide |
cations |
metal oxyanions |
|
PO43- |
phosphate |
|
HPO42- |
hydrogen phosphate |
|
H2PO4- |
dihydrogen phosphate |
|
|
CN- |
cyanide |
|
OCN- |
cyanate |
|
SCN- |
thiocyanate |
|
|
|
CrO42- |
chromate |
|
Cr2O72- |
dichromate |
|
MnO4- |
permanganate |
|
|
oxygen |
organics |
|
OH- |
hydroxide |
|
O22- |
peroxide |
|
|
|
 |
If
you can remember the formula of the ion whose name ends with ate,
you can usually work out the formulas of the other family members
as follows:
|
modify stem name with: |
meaning |
examples |
|
-ate |
a common form, containing oxygen |
chlorate, ClO3-
nitrate, NO3-
sulfate, SO42- |
|
-ite |
one less oxygen than -ate form |
chlorite, ClO2-
sulfite, SO32-
nitrite, NO2-
|
|
per-, -ate |
same charge, but contains one more oxygen than -ate form |
perchlorate, ClO4-
perbromate, BrO4-
|
|
hypo-, -ite |
same charge, but contains one less oxygen than the -ite
form |
hypochlorite, ClO-
hypobromite, BrO- |
|
thio- |
replace an O with an S |
thiosulfate, S2O32-
thiosulfite, S2O22- |
Some
anions can capture hydrogen ions. For example, carbonate (CO32-
can capture an H+ to produce hydrogen carbonate HCO3-
(often called bicarbonate). Each captured hydrogen neutralizes one minus
charge on the anion.
|
modify stem name with: |
meaning |
examples |
|
hydrogen
or bi- |
(1) captured H+ ions |
hydrogen carbonate, HCO3- (a.k.a. bicarbonate)
hydrogen sulfate, HSO4- (a.k.a. bisulfate) |
|
dihydrogen |
(2) captured H+ ions |
dihydrogen phosphate, H2PO4-
|
|
Table of common
polyatomic cations, arranged by charge. Alternate names are given in italics. Select the
name of the ion for information about its occurrence, uses, properties, and
structure.
|
+2 |
|
Hg22+ |
mercury(I) or mercurous |
|
 |
|
+1 |
|
NH4+ |
ammonium |
|
H3O+ |
hydronium |
|
|
-1 |
|
C2H3O2- |
acetate |
|
ClO3- |
chlorate |
|
ClO2- |
chlorite |
|
CN- |
cyanide |
|
H2PO4- |
dihydrogen phosphate |
|
HCO3- |
hydrogen carbonate
or bicarbonate |
|
HSO4- |
hydrogen sulfate
or bisulfate |
|
OH- |
hydroxide |
|
ClO- |
hypochlorite |
|
NO3- |
nitrate |
|
NO2- |
nitrite |
|
ClO4- |
perchlorate |
|
MnO4- |
permanganate |
|
SCN- |
thiocyanate |
|
|
-2 |
|
CO32- |
carbonate |
|
CrO42- |
chromate |
|
Cr2O72- |
dichromate |
|
HPO42- |
hydrogen phosphate |
|
O22- |
peroxide |
|
SO42- |
sulfate |
|
SO32- |
sulfite |
|
S2O32- |
thiosulfate |
|
 |
|
-3 |
|
PO43- |
phosphate |
|
|
-1 CHARGE |
-2 CHARGE |
-3 CHARGE |
-4 CHARGE |
|
ion |
name |
ion |
name |
ion |
name |
ion |
name |
|
H2PO3- |
dihydrogen phosphite |
HPO32- |
hydrogen phosphite |
PO33- |
phosphite |
P2O74- |
pyrophosphate |
|
H2PO4- |
dihydrogen phosphate |
HPO42- |
hydrogen phosphate |
PO43- |
phosphate |
|
|
|
HCO3- |
hydrogen carbonate |
CO32- |
carbonate |
PO23- |
hypophosphite |
|
|
|
HSO3- |
hydrogen sulfite |
SO32- |
sulfite |
AsO33- |
arsenite |
|
|
|
HSO4- |
hydrogen sulfate |
SO42- |
sulfate |
AsO43- |
arsenate |
|
|
|
NO2- |
nitrite |
S2O32- |
thiosulfate |
|
|
|
|
|
NO3- |
nitrate |
SiO32- |
silicate |
|
|
|
|
|
OH- |
hydroxide |
C22- |
carbide |
|
|
|
|
|
CH3COO- |
acetate |
C2O42- |
oxalate |
|
|
|
|
|
CrO2- |
chromite |
CrO42- |
chromate |
|
|
|
|
|
CN- |
cyanide |
Cr2O72- |
dichromate |
|
|
|
|
|
CNO- |
cyanate |
C4H4O62- |
tartrate |
|
|
|
|
|
CNS- |
thiocyanate |
MoO42- |
molybdate |
|
|
|
|
|
O2- |
superoxide |
O22- |
peroxide |
|
|
|
|
|
MnO4- |
permanganate |
S22- |
disulfide |
|
|
|
|
|
ClO- |
hypochlorite |
|
|
|
|
|
|
|
ClO2- |
chlorite |
|
|
|
|
|
|
|
ClO3- |
chlorate |
|
|
|
|
|
|
|
ClO4- |
perchlorate |
|
|
|
|
|
|
|
BrO- |
hypobromite |
|
|
|
|
|
|
|
BrO2- |
bromite |
|
|
|
|
|
|
|
BrO3- |
bromate |
|
|
|
|
|
|
|
BrO4- |
perbromate |
|
|
|
|
|
|
|
IO- |
hypoiodite |
|
|
|
|
|
|
|
IO2- |
iodite |
|
|
|
|
|
|
|
IO3- |
iodate |
|
|
|
|
|
|
|
IO4- |
periodate |
|
|
|
|
|
|
|
AlO2- |
aluminate |
|
|
|
|
|
|
|
N3- |
azide |
|
|
|
|
|
|

Newscripts October 31, 2005 Volume 83, Number 44 p. 52
Army Humvees Can Produce Water
Delivery of water to an army in the desert is a costly and time-consuming effort. The military calculates that a soldier in the desert needs 20 gal of water a day, five of which must be pure enough to drink. It can take up to 40% of troops deployed in the field just to transport water and other materials, so it would be a great advance if another source of water were available. That source might be vehicle exhaust. Engineers at United Technologies Corp.'s Hamilton Sundstrand unit are building two Humvees for the Army that will extract and clean water directly from the exhaust. Although the idea is not new, the Army has spent millions to make it work. The water vapor and other gases in the exhaust from the modified Humvees are vented through a catalytic converter to eliminate as many impurities as possible, and then run through a pair of heat exchangers to condense the water. This blackish liquid is then passed through a series of six proprietary carbon filters that bring the quality up to about tap water. Finally, chlorine is added to kill bacteria and algae, and the water flows into a 5-gal tank with a spigot. The water can be chilled by the Humvee's air conditioner. It is estimated that a vehicle could produce about 1 gal of water for each 2 gal of diesel fuel burned. The company recognizes that a lot of development still needs to be done. The system can cost more than 20% of the cost of the vehicle, it weighs almost 500 lb, and the water filters need to be changed every 75 to 200 gal. Still, if such a system can help soldiers survive if they cannot get other logistical support, it sounds like a good idea.
You might be from the Northwest if you...
Know the state flower (Mildew).
Feel guilty throwing aluminum cans or paper in the trash.
Use the statement "sun break" and know what it means.
Know more than 10 ways to order coffee.
Know more people who own boats than air conditioners.
Feel overdressed wearing a suit to a nice restaurant.
Stand on a deserted corner in the rain waiting for the "WALK" signal.
Consider that if it has no snow or has not recently erupted, it is not a real mountain.
Can taste the difference between Starbucks, Seattle's Best, and Veneto's.
Know the difference between Chinook, Coho, and Sockeye salmon.
Know how to pronounce Sequim, Puyallup, Issaquah, Oregon, and Willamette.
Consider swimming an indoor sport.
In winter, go to work in the dark and come home in the dark, while only working eight-hour days.
Never go camping without waterproof matches and a poncho.
Are not fazed by "Today's forecast: showers followed by rain," and "Tomorrow's forecast: rain followed by showers."
Cannot wait for a day with "showers and sun breaks."
Have no concept of humidity without precipitation.
Know that Boring is a town in Oregon and not just a state of mind.
Can point to at least two volcanoes, even if you cannot see through the cloud cover.
Notice "the mountain is out" when it is a pretty day and you can actually see it.
Put on your shorts when the temperature gets above 50, but still wear your hiking boots and parka.
Switch to your sandals when it gets about 60, but keep the socks on.
Have actually used your mountain bike on a mountain.
Think people who use umbrellas are either wimps or tourists.
Knew immediately that the view out of Frasier's window was fake.
Buy new sunglasses every year, because you can't find the old ones after such a long time.
Measure distance in hours.
Often switch from "heat" to "a/c" in the same day.
Use a down comforter in the summer.
Design your kid's Halloween costume to fit over a raincoat.
Know all the important seasons: Almost Winter, Winter, Still Raining (Spring), Road Construction (Summer), Deer & Elk season (Fall).
Actually understand these jokes and send them to all your friends in the northwest or those who used to live here!

Tables of lots of polyatomic ions
| The 9 polyatomic ions to know and write on your notecard: |
| Name |
Charge |
Formula |
| Hydroxide |
1- |
OH- |
| Cyanide |
1- |
CN- |
| Nitrate |
1- |
NO3- |
| Acetate |
1- |
CH3COO- |
| Carbonate |
2- |
CO32- |
| Phosphate |
3- |
PO43- |
| Hydronium |
1+ |
H3O+ |
| Ammonium |
1+ |
NH4+ |
| Sulfate |
2- |
SO42- |
Balancing reactions:

Trio shares Nobel prize for chemistry
Frenchman, 2 Americans honored for reducing hazardous chemical waste
Updated: 6:11 a.m. ET Oct. 5, 2005
STOCKHOLM, Sweden - France's Yves Chauvin and Americans Robert H. Grubbs and Richard R. Schrock won the 2005 Nobel Prize in chemistry Wednesday, for their work to reduce hazardous waste in forming new chemicals.
The trio won the award for their development for the metathesis method in organic synthesis.
The Nobel Prize committee honored the laureates for their findings in metathesis, which focuses on how chemical bonds are broken and made between carbon atoms.
The process is used "daily in the chemical industry, mainly in the development of pharmaceuticals and advanced plastic materials."
"This represents a great step forward for 'green chemistry,' reducing potentially hazardous waste through smarter production. Metathesis is an example of how important basic science has been applied for the benefit of man, society and the environment," the committee said.
© 2005 The Associated Press.
|
 |
The Nobel Prize in Chemistry 2005 |
| "for the development of the metathesis method in organic synthesis" |
| |
 |
 |
 |
| Yves Chauvin |
Robert H. Grubbs |
Richard R. Schrock |
1/3 of the prize |
1/3 of the prize |
1/3 of the prize |
| France |
USA |
USA |
| |
|
|
Institut Français du Pétrole
Rueil-Malmaison, France |
California Institute of Technology (Caltech)
Pasadena, CA, USA |
Massachusetts Institute of Technology (MIT)
Cambridge, MA, USA |
| b. 1930 |
b. 1942 |
b. 1945 |
|
http://nobelprize.org/
|
 |
The Nobel Prize in Physics 2005 |
| "for his contribution to the quantum theory of optical coherence" |
"for their contributions to the development of laser-based precision spectroscopy, including the optical frequency comb technique" |
| |
 |
 |
 |
| Roy J. Glauber |
John L. Hall |
Theodor W. Hänsch |
1/2 of the prize |
1/4 of the prize |
1/4 of the prize |
| USA |
USA |
Germany |
| |
|
|
Harvard University
Cambridge, MA, USA |
University of Colorado, JILA; National Institute of Standards and Technology
Boulder, CO, USA |
Max-Planck-Institut für Quantenoptik
Garching, Germany; Ludwig-Maximilians-Universität
Munich, Germany |
| b. 1925 |
b. 1934 |
b. 1941 |
|

Honda Designs Car Friendly for Dogs
The text and solutions guide have been placed on reserve at the library:
# Title Barcode Call Num Author Status Until Location Checkouts
1 General 1201435386 VR 81 Ebbing; Active 09-05-2006 vrbl 0
Chemistry, 72 Gammon
8th ed
2 Solutions 1201435385 VR 82 Bookin, Active 09-05-2006 vrbl 0
Manual 73 David
for
General
Chemistry,
8th ed
Please inform your students that course reserves are filed by the call number or the VR number listed above.
Worksheet 1 will be discussed in recitation during Week 1. A copy was provided during the first lecture meeting. Click here to view/download.
| The 9 polyatomic ions to know and write on your notecard: |
| Name |
Formula |
| Hydroxide |
OH- |
| Cyanide |
CN- |
| Nitrate |
NO3- |
| Acetate |
CH3COO- |
| Carbonate |
CO32- |
| Phosphate |
PO43- |
| Hydronium |
H3O+ |
| Ammonium |
NH4+ |
| Sulfate |
SO42- |
Exam 1 Study Tips:
Worksheets
Past Exams
Notes
ChemSkill Builder
Study in small groups
Sample Standard Enthalpies of Formation Table--See Table 6.2 in your text:

Study Tips:
Worksheets
Past Exams
Notes