| John C. Westall |
Analytical Chemistry |
Research Interests
Dr. Westall's research is focused on the
application of surface and solution chemistry to problems in
environmental chemistry, electrochemistry, and analytical chemistry.
Current research topics include: (i) interactions of metal ions with
heterogeneous environmental complexants, such as humic substances and
surfaces of soil particles, and development of models for these complex
interactions; (ii) electrochemical processes in the environment,
including corrosion and redox transformations of inorganic and organic
pollutants; (iii) the processes that control the distribution of
hydrophobic, ionogenic, and ionic organic compounds between water and
environmental sorbents; (iv) electric double layer phenomena associated
with environmental surfaces; (v) mathematical methods for the
determination of equilibrium constants from experimental data; (vi) the
application of multicomponent chemical equilibrium models to
biogeochemical problems. Dr. Westall retired in 2008. He is still working on collaborative research projects but is no longer accepting new graduate students.
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Representative Publications
- Substrate degradation kinetics, microbial diversity, and current efficiency of microbial fuel cells supplied with marine plankton, Appl. Envir. Microbiology, 2007, 73 (21), 7029-7040.
- U(VI) adsorption on natural iron-coated sands: comparison of approaches for modeling adsorption on heterogenous environmental materials, Appl. Geochem., 2004, 19 (12), 1937-1951.
- Role of
Surface Alteration in Determining the Mobility of U(VI) in the Presence of Citrate:
Implications for Extraction of U(VI) from Soils, Environ. Sci. Technol.,
2004, 38, 3752-3759.
- Kinetics of
Reduction of Nitrobenzene and Carbon Tetrachloride at an Iron-Oxide Coated Gold Electrode,
Environ. Sci. Technol., 2003, 37, 2356-2362.
- Mass Transport
Effects on the Kinetics of Nitrobenzene Reduction by Iron Metal, Environ. Sci.
Technol., 2001, 35, 2804-2811.
- Evaluation of Liposome-Water Partitioning of Organic Acids and Bases:
1. Development of a Sorption
Model,
2. Comparison of
Experimental Determination Methods, Environ. Sci. Technol., 2000,
34, 3954-3968.
- Sorption of
Linear Alkylbenzenesulfonates on Sediment Materials, Environ. Sci. Technol.,
1999, 33, 3110-3118.
- Sequestration
of Hydrophobic Organic Contaminants by Geosorbents - Critical Review, Environ. Sci.
Technol., 1997, 31, 3341
- Models for Association of Metal Ions with Heterogeneous Environmental
Sorbents: I. Complexation of Co(II) by Leonardite Humic Acid as a Function of pH and
NaClO4 Concentration, Environ. Sci. Technol., 1995, 29,
951.
- Use of Cationic Surfactants to Modify Soil Surfaces To Promote
Sorption and Retard Migration of Hydrophobic Organic Compounds, Environ. Sci.
Technol., 1994, 28, 231.
- The Study of Soil Chemistry Through Quasi-Steady-State Models: II.
Acidity of Soil Solution, Geochim. Cosmochim. Acta, 1990, 54, 2363.
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